Hydrosilylation
Hydrosilylation, also called catalytic hydrosilation, describes the addition of Si-H bonds across unsaturated bonds. Ordinarily the reaction is conducted catalytically and usually the substrates are unsaturated organic compounds. Alkenes and alkynes give alkyl and vinyl silanes; aldehydes and ketones give silyl ethers. Hydrosilylation has been called the "most important application of platinum in homogeneous catalysis." The process was first reported in academic literature in 1972.

This is an excerpt from the article Hydrosilylation from the Wikipedia free encyclopedia. A list of authors is available at Wikipedia.
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Hydrosilylation - Wikipedia, the free encyclopedia
Hydrosilylation, also called catalytic hydrosilation, describes the addition of Si-H bonds across unsaturated bonds. Ordinarily the reaction is conducted ...
en.wikipedia.org/wiki/Hydrosilylation
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Hydrosilylation Catalyst in Chemical Synthesis | Sigma-Aldrich
A Highly Efficient Hydrosilylation Catalyst, sigma-aldrich is pleased to offer [Cp* Ru(MeCN)3]PF6, as well as a number of other catalysts for Hydrosilylation.
www.sigmaaldrich.com/chemistry/chemical-synthesis/technology-spotlights/hydrosilylation-catalyst.html
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Alkyne Hydrosilylation | Sigma-Aldrich
Of the available methods for preparation of vinylsilanes, the Hydrosilylation of alkynes is the most direct and atom-economical approach (Scheme 1). A number  ...
www.sigmaaldrich.com/technical-documents/articles/chemfiles/alkyne-hydrosilylation.html
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Chapter 7 Hydrosilylation of Carbon-Carbon Double Bonds - Springer
Chapter 7. Hydrosilylation of Carbon-Carbon Double Bonds. Tamio Hayashi. Department of Chemistry, Faculty of Science, Kyoto University, Sakyo, Kyoto ...
static.springer.com/sgw/documents/97394/application/pdf/3540643362-c1.pdf
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Phosphinite-Iminopyridine Iron Catalysts for Chemoselective Alkene ...
Dec 4, 2013 ... These iron compounds are efficient and selective catalysts for the anti- Markovnikov alkene Hydrosilylation of primary, secondary, and tertiary ...
pubs.acs.org/doi/abs/10.1021/ja404963f
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Olefin Isomerization and Hydrosilylation Catalysis by Lewis Acidic ...
Nov 20, 2013 ... In the presence of hydrosilanes, olefins and alkynes undergo efficient Hydrosilylation catalysis to the alkylsilanes. Experimental and ...
pubs.acs.org/doi/abs/10.1021/ja410379x
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Surface-Induced Alkene Oligomerization: Does Thermal ...
Oct 28, 2013 ... Surface functionalization of hydride-terminated silicon nanocrystals (SiNCs) with dodecene via thermal Hydrosilylation has been reexamined.
pubs.acs.org/doi/abs/10.1021/ja409657y
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Illuminating Silicon Surface Hydrosilylation: An Unexpected Plurality ...
Sep 6, 2013 ... Hydrosilylation, the insertion of an alkene or alkyne into a surface Si–H bond, is an ideal approach to producing these covalent Si–C bonds, ...
pubs.acs.org/doi/abs/10.1021/cm402120f
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SiliaCat - Hydrosilylation Applications | SiliaCat ... - Silicycle
Hydrosilylation reactions (or catalytic hydrosilation) are a widely used method to prepare organosilicon products. The reaction consists of the addition of Si-H ...
www.silicycle.com/products/siliacat-heterogeneous-catalysts/siliacat-applications/siliacat-hydrosilylation-applications
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Ruthenium catalyzed selective hydrosilylation of aldehydes ...
A chemoselective Hydrosilylation method for aldehydes is developed using a ruthenium catalyst [(Ru(p-cymene)Cl2)2] and triethylsilane; a mono hydride ...
pubs.rsc.org/en/content/articlelanding/2013/cc/c3cc47593j
Search results for "Hydrosilylation"
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Hydrosilylation in science
Platinum catalysed hydrosilylation of propargylic alcohols - Queen's ...
May 10, 2013 ... Queen's University Belfast · Study at Queen's · Research ... Platinum catalysed Hydrosilylation of propargylic alcohols. Research output: ...
Illuminating Silicon Surface Hydrosilylation: An Unexpected Plurality ...
Sep 6, 2013 ... Department of Chemistry, University of Alberta, Edmonton, Alberta T6G ... Hydrosilylation, the insertion of an alkene or alkyne into a surface ...
Effect of triarylphosphane ligands on the rhodium-catalyzed ...
Jan 15, 2014 ... Effect of triarylphosphane ligands on the rhodium-catalyzed Hydrosilylation of alkene. Mei Xue,; Jiayun Li,; Jiajian Peng,; Ying Bai,; Guodong ...
Iron-Catalysed Chemo-, Regio-, and Stereoselective Hydrosilylation ...
Feb 2, 2014 ... The chemo-, regio-, and stereoselective iron-catalysed Hydrosilylation of alkenes and alkynes with excellent functional group tolerance is ...
Competitive hydrosilylation in carbon nanoreactors: probing the ...
aSchool of Chemistry, University of Nottingham, University Park, Nottingham, ... In this study, we employ competitive Hydrosilylation reactions catalysed by Pt ...
The synergistic effect of nanoporous AuPd alloy catalysts on highly ...
The nanoporous AuPd (AuPdNPore) alloy catalyst showed superior chemoselectivity and high catalytic activity for the direct 1,4-Hydrosilylation of the conjugated ...
Find experts by concept Hydrosilylation - University of Minnesota ...
Find the right expert or researcher from University of Minnesota on Hydrosilylation. Hydrosilylation SciVal Experts.
University of Waterloo announces a licensing agreement with ...
University of Waterloo announces a licensing agreement with Milliken & Company for its technology on Hydrosilylation of Polypropylene targeted for additives ...
Books on the term Hydrosilylation
Hydrosilylation: A Comprehensive Review on Recent Advances
Hydrosilylation: A Comprehensive Review on Recent Advances
Bogdan Marciniec, 2008
Finally, this book provides an excellent review of Hydrosilylation processes and their products thus making this book a useful handbook for post-graduate students working in catalysis, organometallic chemistry as well as synthesis and the ...
Hydrosilylation: A Comprehensive Review on Recent Advances (Advances in Silicon Science)
Hydrosilylation: A Comprehensive Review on Recent Advances (Advances in Silicon Science)
2008
For fifty years, Hydrosilylation has been one of the most fundamental and elegant methods for the laboratory and industrial synthesis of organosilicon and silicon related compounds. Despite the intensive research and continued interest generated by organosilicon compounds, no comprehensive book incorporating its various aspects has been published t...
I. Copper Hydride Catalyzed Asymmetric Hydrosilylation of ...
I. Copper Hydride Catalyzed Asymmetric Hydrosilylation of ...
Asher Lower, 2006
A variety of substituted olefins can be made via the stereoselective zirconium-catalyzed carboalumination of terminal alkynes.
Comprehensive Handbook on Hydrosilylation
Comprehensive Handbook on Hydrosilylation
1992
This handbook provides an up-to-date account of Hydrosilylation reactions and the directions in which synthetic and mechanistic studies as well as practical applications of these processes are proceeding. The book consists of two parts: the first is descriptive, presenting the catalytic, mechanistic, structural and synthetic aspects of hydrosilylat...
Comprehensive handbook on hydrosilylation
Comprehensive handbook on hydrosilylation
Bogdan Marciniec, 1992
This handbook provides an up-to-date account of Hydrosilylation reactions and the directions in which synthetic and mechanistic studies as well as practical applications of these processes are proceeding.
Organotransition Metal Chemistry: From Bonding to Catalysis
Organotransition Metal Chemistry: From Bonding to Catalysis
John Hartwig, 2009
Organotransition Metal Chemistry From Bonding to Catalysis provides a selective, but thorough and authoritative coverage of the fundamentals of organometallic chemistry, the elementary reactions of these complexes, and many catalytic processes occurring through organometallic intermediates. Built upon the foundation established by the classic text ...
Troticene Lithiation and Platinum-catalyzed Hydrosilylation ...
Troticene Lithiation and Platinum-catalyzed Hydrosilylation ...
Rhyan Joseph Soriano Terrado, 2009
Hydrosilylation reactions of bis(dimethylsilyl)-ferrocene or troticene gave lower beta(E)- to alpha-olefinic proton ratios compared to dimethylsilyl-ferrocene or troticene, the latter two giving regiochemical distributions consistent with ...
Hydrosilylation: Webster's Timeline History, 1986 - 2007
Hydrosilylation: Webster's Timeline History, 1986 - 2007
2010
Webster's timelines cover bibliographic citations, patented inventions, as well as non-conventional and alternative meanings which capture ambiguities in usage. These furthermore cover all parts of speech (possessive, institutional usage, geographic usage) and contexts, including pop culture, the arts, social sciences (linguistics, history, ge...
Silicon-Containing Dendritic Polymers (Advances in Silicon Science)
Silicon-Containing Dendritic Polymers (Advances in Silicon Science)
2009
During the last two decades silicon-containing dendritic polymers have become one of the fastest growing areas of development in polymer science. The eruption of interest in these new polymers stems from their unprecedented molecular architecture, unique resulting properties and the realization that they represent ideal building blocks for chemical...
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Blog posts on the term
Hydrosilylation
HOT Article: Understanding hydrosilylation « Dalton Transactions Blog
Hiromi Tobita and colleagues look into the reactions of bis(silyl)hydrido molybdenum and tungsten complexes in this Dalton Transactions Hot article. They were able to generate a 16-electron species, which when reacted with nitriles led to Hydrosilylation of their CN triple bonds to give N-silylimine complexes, even at room temperature. Synthesis and characterisation of hydrido molybdenum and tungsten complexes having a hemilabile tridentate Si,Si,O-ligand: observation of stepwise Hydrosilylation of a nitrile to form an N-silylimine on the metal centre Takashi Komuro, Rockshana Begum, Rikima Ono and Hiromi TobitaDalton Trans., 2011, Advance Article DOI: 10.1039/C0DT01047B, Paper READ FOR FREE until 11th January.
blogs.rsc.org/dt/2010/12/15/hot-article-understanding-hydrosilylation/
A metal-free catalytic intramolecular hydrosilylation - Canadian Journal of Chemistry
www.nrcresearchpress.com/doi/abs/10.1139/v03-121
Organometallic Chemistry News: Iron-Catalyzed Hydrosilylation of Esters
David Bézier, Gopaladasu T. Venkanna, Luis C.
organometallicchemistrynews.blogspot.com/2012/07/iron-catalyzed-hydrosilylation-of-esters.html
An-Najah Blogs : Hydrosilylation reactions catalyzed by transition-metal complexes
Hydrosilylation reactions catalyzed by transition-metal complexes
blogs.najah.edu/staff/hikmat-hilal/article/Hydrosilylation-reactions-catalyzed-by-transition-metal-complexes
An-Najah Blogs : Hydrosilylation reactions catalyzed by Mn2(CO)10
Hydrosilylation reactions catalyzed by Mn2(CO)10
blogs.najah.edu/staff/hikmat-hilal/article/H-9
hydrosilylation - Did you spell it correctly. Alternative spellings in the American English Dictionary - Cambridge Dictionaries Online (US)
Hydrosilylation - Did you spell it correctlly? Alternative spellings. See more in the American English Dictionary - Cambridge Dictionaries Online (US)
dictionary.cambridge.org/us/spellcheck/american-english/?q=hydrosilylation
Angamuthu Group Literature Blog: Effective Fixation of CO2 by Iridium-Catalyzed Hydrosilylation
angamuthu-group-literature.blogspot.com/2012/09/effective-fixation-of-co2-by-iridium.html
Hydrosilylation | Syntheticnature
Posts about Hydrosilylation written by syntheticnature
syntheticnature.wordpress.com/tag/hydrosilylation/
UCL Discovery - Titanocene-Catalyzed Hydrosilylation of Imines: Experimental and Computational Investigations of the Catalytically Active Species
discovery.ucl.ac.uk/172109/
UCL Discovery - Further observations on the rhodium (I)-catalysed tandem hydrosilylation-intramolecular aldol reaction
discovery.ucl.ac.uk/74398/
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