Organosodium
Organosodium chemistry is the chemistry of organometallic compounds containing a carbon to sodium chemical bond. The application of organosodium compounds in chemistry is limited in part due to competition from organolithium compounds, which are commercially available and exhibit more convenient reactivity.
The principal organosodium compound of commercial importance is sodium cyclopentadienide. Sodium tetraphenylborate can also be classified as an organosodium compound since in the solid state sodium is bound to the aryl groups.
Organometal bonds in group 1 are characterised by high polarity with corresponding high nucleophilicity on carbon. This polarity results from the disparate electronegativity of carbon (2.55) and that of lithium 0.98, sodium 0.93 potassium 0.82 rubidium 0.82). The carbanionic nature of organosodium compounds can be minimized by resonance stabilization, for example, Ph3CNa. One consequence of the highly polarized Na-C bond is that simple organosodium compounds tend to aggregate and are often poorly soluble.

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Organosodium chemistry - Wikipedia, the free encyclopedia
Organosodium chemistry is the chemistry of organometallic compounds containing a carbon to sodium chemical bond. The application of Organosodium  ...
en.wikipedia.org/wiki/Organosodium_chemistry
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Organosodium Compounds for Preparation of Other Carbon-Metal ...
The history and preparation of organometallic compounds are discussed. The reactions of Organosodium compounds with various metal chlorides are given, ...
pubs.acs.org/doi/abs/10.1021/ba-1959-0023.ch006
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Organosodium chemistry - Saylor.org
Organosodium chemistry. 1. Organosodium chemistry. Organosodium chemistry is the chemistry of organometallic compounds containing a carbon to sodium ...
www.saylor.org/site/wp-content/uploads/2011/06/Organosodium-Chemistry.pdf
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Organosodium and Organopotassium Compounds. Part II ...
Organosodium and Organopotassium Compounds. Part 11: Preparation and Synthetic Applications [I1. BY DR. M. SCHLOSSER. UNION CARBIDE EUROPEAN ...
onlinelibrary.wiley.com/doi/10.1002/anie.196403621/pdf
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Organosodium and Organopotassium Compounds Part I: Properties ...
Organosodium and Organopotassium Compounds. Part I: Properties and Reactions [l]. BY DR. M. SCHLOSSER. UNION CARBIDE EUROPEAN RESEARCH ...
onlinelibrary.wiley.com/doi/10.1002/anie.196402871/pdf
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Organolithium and organosodium compounds: the second ...
posed that organolithium and Organosodium compounds are very likely to lead to materials with the required very large nonlinearities, which are necessary in ...
www.tandfonline.com/doi/pdf/10.1080/002689797170293
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NMR spectra of a hydrocarbon-soluble organosodium ... - Springer
838. Russian Chemical Bulletin, VoL 45, No. 4, April, 1996. NMR spectra of a hydrocarbon-soluble Organosodium compound and its lithium analogs. IV.
link.springer.com/content/pdf/10.1007%2FBF01431309.pdf
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Organolithium, organosodium, and organomagnesium compounds ...
Feb 1, 1988 ... The results of research on the synthesis and transformations of metallated azoles that contain the metal (lithium, sodium, magnesium) in the ...
link.springer.com/article/10.1007%2FBF00473317
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organosodium - Wiktionary
Adjective[edit]. Organosodium (not comparable). (organic chemistry) Describing any organic compound containing a carbon to sodium bond. Retrieved from ...
en.wiktionary.org/wiki/organosodium
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Sodium cyclopentadienide - Wikipedia, the…
Sodium cyclopentadienide is an Organosodium compound with the formula C 5 H 5 Na. The compound is often abbreviated as NaCp or CpNa, where Cp − is the ...
en.wikipedia.org/wiki/Sodium_cyclopentadienide
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Organosodium in science
[PDF]The Conductance of Non-Aqueous Solutions. III. Some Organo ...
[CONTFSEUTION FROM TEE '&EMICAL. LABORATORY. OF HARVARD UNIVERSITY]. The Conductance of Non-Aqueous Solutions. III. Some Organo-sodium ...
13 C and 23 Na solid-state NMR spectra of organosodium compounds
Mar 31, 2003 ... For three Organosodium complexes, namely triphenylmethylsodium(tmeda) (1), fluorenylsodium(pmdta) (2) and fluorenylsodium(tmeda) (3), ...
[PDF]13C and 23Na solid-state NMR spectra of organosodium compounds
University of Siegen, FB8, D-57068 Siegen, Germany ... For three Organosodium complexes, namely triphenylmethylsodium(tmeda) (1), fluorenylsodium(pmdta).
First Structure of a Mixed Organosodium/Lithium Alkoxide ...
Dec 22, 2003 ... Li [BOND] O interactions dominate the structure of 1, a molecule that contains the M [BOND] C and Li [BOND] O functionalities suspected to play ...
[PDF]Organolithium and organosodium compounds: the second ...
Chemistry Department, University of Ioannina, Ioannina 451 10, Greece ... posed that organolithium and Organosodium compounds are very likely to lead to ...
13C and 23Na solid‐state NMR spectra of organosodium compounds
Publication » 13C and 23Na solid‐state NMR spectra of Organosodium compounds. ... University of Siegen, FB8, D-57068 Siegen, Germany. Magnetic ...
[PDF]Organolithium and organosodium compounds of 1,2 ... - Springer
ORGANOLITHIUM AND Organosodium ... (THF) at O~ to give organolithium and Organosodium compounds IIa-f, which are ... Rostov State University.
Organolithium and organosodium compounds of n-substituted 2 ...
Aug 1, 1986 ... Organolithium and Organosodium compounds of 1,2-dimethyl-, ... and Organic Chemistry, M. A. Suslov Rostov State University, Rostov-on-Don ...
Organosodium compounds of N-substituted benzimidazoles - Springer
Sep 1, 1971 ... Some transformations of the Organosodium compounds of N-substituted benzimidazoles were ... 1. Rostov State University, Rostov-on-Don ...
Organolithium and organosodium compounds of 1,2 ... - Springer
Dec 1, 1976 ... Organolithium and Organosodium compounds of 1,2- ... Institute of Physical and Organic Chemistry, Rostov State University, Rostov-on-Don ...
Books on the term Organosodium
Mechanism and Synthesis
Mechanism and Synthesis
Peter Taylor, 2002
By analogy with the formation ofGrignard reagents and organolithium compounds, we might expect Organosodium compounds to be made by reacting a haloalkane with sodium; however, this reaction does not happen. Unlike organolithiums ...
Organometallics in Synthesis, Third Manual
Organometallics in Synthesis, Third Manual
Manfred Schlosser, 2013
This latest edition enables readers to master new classes of organometallic compounds and synthesesA popular resource used by synthetic organic chemists around the world, this book enables readers to conduct seamless synthetic reactions involving key organometallics. Each reaction is set forth in the book's acclaimed recipe-style format so tha...
Main-Group Metal Organometallics in Organic Synthesis
Main-Group Metal Organometallics in Organic Synthesis
Edward W. Abel, F. G. A. Stone, Alexander McKillop, 1995
concerned with the chemistry of Organosodium and organopotassium compounds and none of them has been published since the mid-1960s. In detail, two reviews by Schlosser published in 19647 are the most recent, following the articles by ...
Mechanism and Synthesis
Mechanism and Synthesis
Giles Clark, The Open University, P G Taylor and Lesley E Smart, 2003
This book pursues possible strategies for synthesising mainly organic compounds, particularly those of interest to the health sector and related industries. Topics covered include addition reactions of aldehydes and ketones; the use of organometallic reagents to form carbon-carbon bonds (eg Grignard reagents); and radical reactions, including selec...
Dictionary of Organometallic Compounds
Dictionary of Organometallic Compounds
Jane E. Macintyre, 1994
22.98977 Electronic Configuration. [Ne] 35 ' Oxidation State. 1 Coordination Number. Not much structural information is available on simple Organosodium compounds, although structures of some sodium amides and related compounds have ...
Organometallics in Synthesis, Third Manual
Organometallics in Synthesis, Third Manual
Manfred Schlosser, 2013
This latest edition enables readers to master new classes of organometallic compounds and synthesesA popular resource used by synthetic organic chemists around the world, this book enables readers to conduct seamless synthetic reactions involving key organometallics. Each reaction is set forth in the book's acclaimed recipe-style format so tha...
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Organosodium
ORGANOMETALLIC COMPOUNDS
organohalogen compounds is the formation of organometallic compounds by replacement of the halogen by a metal atom.
www.organicchemistry.com/organometallic-compounds/
Avery Morton – synthetic chemist extraordinaire | Solarsaddle's Blog
The latest Classic Kit column goes online some time in the next 48 hours. It's about Avery Adrian Morton, a brilliant synthetic chemist who specialized in heterocycles, but who first figured out how to make Organosodium compounds and who came up with a flask design that includes creases to maximize turbulence. While getting the article…
solarsaddle.wordpress.com/2010/06/30/avery-morton-synthetic-chemist-extraordinaire/
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stupalith: The basic uses about Sodium Hydride
CAS NO. 7646-69-7 FORMULA NaH MOL WT.
stupalith.blogspot.com/2012/07/basic-uses-about-sodium-hydride.html
What is “Alkali metal” ? - LifeSun
Alkali metal The alkali metals are a group in the periodic table consisting of the chemical elements lithium, sodium (Na),[note 1] potassium (K),[note 2] rubidium (Rb), caesium (Cs),[note 3] and francium
lifesun.info/what-is-alkali-metal/
Laboratory Sciences - Nobel Prize winners
Laboratory Sciences - Nobel Prize winners -
lablator.blogfa.com/post/32
World Minerals: Borax And Related Borates
Borax And Related Borates Hydrated sodium borate Na2B4O7 -10H2OBorax fuses at a low temperature and easily dissolves in different important elements like copper, chromium, cobalt, iron, nickel, and uranium giving different characteristic colours. The History Says Borax mining in the United States started with the production of borax from Borax lake in Tehama County in 1864.
worldminerals.blogspot.com/2008/10/borax-and-related-borates.html
Young couples Using A Troubled Bond Should preferably Get Matrimony Advice|The Results of that Drama-Filled Approach to
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Buy Wines Online: New baby pictures!
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